Product ID:AUTOMOTIVE GASOLINE: REGULAR UNLEADED, PREM
MSDS Date:02/01/1990
FSC:9130
NIIN:01-282-2844
MSDS Number: BKSYN

FARMERS UNION CENTRAL EXCHANGE INC.

5500 CENEX DR CENEX MS 530
ST PAUL, MN 55164-0089
US

Emergency Phone: 612-451-5151/800-424-9300(CHEMTREC)

Info Phone: 612-451-5151

Cage: 5Z134

FARMERS UNION CENTRAL EXCHANGE INC

64089 ST PAUL, MN 55164-0089 US

Telephone: 612-451-5151

Cage: 5Z134

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <12%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 50-80%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-3%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: <2%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CUMENE (SARA III)

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: <2%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 50 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 10-15%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10-20%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ANTIOXIDANT (5-15 LBS/1000BBLS)

Fraction By Weight: ABOVE

METAL DEACTIVATOR (1-3 LBS/1000 BBLS)

Fraction By Weight: ABOVE

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATION, CENTRAL NERVOUS
SYSTEM EFFECTS. GASOLINE IF SWALLOWED, MAY BE ASPIRATED INTO LUNGS,
RESULTING IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS. CHRONIC:
DERMATITIS. BENZENE IS A CONFIRME D CARCINOGEN AND MAY PRODUCE
BLOOD CHANGES.
Explanation of Carcinogenicity:BENZENE IS A CONFIRMED CARCINOGEN BY
NTP, IARC AND OSHA.
Effects of Overexposure:EYES/SKIN: SLIGHT IRRITATION. INHALATION:
HEADACHE, NAUSEA, WEAKNESS, SEDATION, AND UNCONSCIOUSNESS.
INGESTION: IRRITATION TO INTESTINES. ASPIRATION INTO LUNG AFTER
INGESTION MAY RESULT IN PULMONARY E DEMA AND CHEMICAL PNEUMONITIS.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF
RESPIRATORY OR SKIN DISORDERS MAY BE AT INCREASED RISK FROM
EXPOSURE.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.SEE DOCTOR.
SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
WATER.SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR.GIVE
OXYGEN/CPR IF NEEDED.SEE DOCTOR. INGESTION: DO NOT INDUCE
VOMITING.SEE DOCTOR IMMEDIATELY. *** NOTE TO PHYSICIAN: GASTRIC
LAVAGE USING CUFFED ENDOTRACHEAL TUBE MAY BE PERFORMED AT YOUR
DISCRETION ***

Flash Point Method:TCC
Flash Point:-50F,-46C
Autoignition Temp:Autoignition Temp Text:536F
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. VAPORS HEAVIER THAN
AIR.CAN TRAVEL A LONG DISTANCE ALONG GROUND & FLASHBACK.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE AREA.
USE NON-SPARKING TOOLS. WEAR PROPER PROTECTIVE EQUIPMENT. STOP
LEAK.ABSORB IN INERT ABSORBENT AND PLACE INTO APPROPIATE DISPOSAL
CONTAINER AND SEAL. WASH AR EA WITH PLENTY OF WATER.

Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
PLACE,AWAY FROM HEAT,IGNITION SOURCES AND INCOMPATIBLE
MATERIALS.KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:AVOID BREATHING VAPORS, AND EYE AND SKIN CONTACT. USE
ONLY WITH ADEQUATE VENTILATION. DO NOT SIPHON BY MOUTH. BOND AND
GROUND CONTAINERS DURING TRANSFER. PROTECT CONTAINERS FROM PHYSICAL
DAMAGE.

Respiratory Protection:NIOSH/MSHA RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE APPROPIATE FOR EXPOSURE OF CONCERN OR SCBA IF TLV IS
EXCEEDED.
Ventilation:SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST
VENTILATION. USE EXPLOSION-PROOF EQUIPMENT.
Protective Gloves:VITON, NITRILE, PVA.
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS TO PREVENT
REPEATED OR PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY
SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN. DO NOT
BREATHE VAPORS. WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING.
Supplemental Safety and Health
THESE PRECAUTIONS ARE FOR NORMAL USES AND CONDITIONS. WHERE SPECIAL OR
UNUSUAL CONDITIONS EXIST, CONSULT AN INDUSTRIAL HYGIENIST. RCRA
CLASSIFICATION IGNITABLE (D001).

HCC:F1
Boiling Pt:B.P. Text:80.0F,26.7C
Vapor Pres:275-475
Vapor Density:3.0-4.0
Spec Gravity:0.65-0.75
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, MOBILE LIQUID WITH CHARACTERISTIC GASOLINE
ODOR. MAY BE COLORED WITH DYE
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:EXPOSURE TO AIR, HIGH HEAT, OPEN FLAMES,
STATIC ELECTRICITY AND OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON OXIDES AND VARIOUS HYDROCARBONS
WHEN BURNED.

Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER.
MANUFACTURER RECOMMENDS INCINERATION OR TRANSFER TO RCRA PERMITTED
WASTE MANAGEMENT FACILITY. DISPOSE OF IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.